Investigation Inhibition Properties of Volatile Atmospheric Corrosion Inhibitor Based on Natural Material

Authors

  • Viktoriya Vorobyova
  • Olena Chygyrynets’
  • Eduard Chygyrynets’

DOI:

https://doi.org/10.20535/1810-0546.2013.1.90672

Abstract

The aim was to study the component composition of the volatile compounds of hops isopropanol extract and evaluation of physical and chemical properties of the new film on the metal surface. The volatiles extract of hope cones are analysed by Gas Chromatography Mass Spectrometry (GC–MS). Based on the data of the gas chromatography-mass spectrometry we identify the qualitative composition of the volatile compounds of the extract hops “Aromatic”. The main components are terpenoids, ketones, phenolic compounds, phenol and phenol carboxylic acid. Hope cones extract is developed as novel volatile corrosion inhibitors and can be used as solution and impregnated paper (VPI paper). We also study the effect of volatile compounds isopropanol extract of the kinetics of the partial electrode reactions. The experimental results show that the investigated extract, which can effectively retard the anodic dissolution of steel, are anodic inhibitors. We discover that the using volatile fractions of the hops extract as an inhibitor leads to formation of the film shifts of corrosion potential in the positive direction and significantly reduces the corrosion rate. The maximum increase in the hydrophobicity and the shift of the corrosion potential in the positive direction is observed after steel pre-treatment for 2 days in vapors of extract volatile compounds.

References

1. Чигиринець О.Е., Воробйова В.І. Дослідження протикорозійної ефективності рослинних екстрактів // Наукові вісті КПІ. — 2010. — № 6. — С. 152—156.

2. Повышение эффективности летучих ингибиторов растительного происхождения / Е.Э. Чигиринец, В.И. Воробьева, Г.Ю. Гальченко и др. // Вісник Чернігівського держ. технолог. ун-ту. — 2011. — № 4. — С. 130—133.

3. Выбор растительного сырья для создания высокоэффективных ингибирующих композиций / Е.Э. Чигиринец, В.И. Воробьева, О.А. Мирянова и др. // Сборник научных статей 3-го Всеукр. съезда экологов с международным участием. — 2011. — № 1. — С. 305—307.

4. A.Y. El-Etre, “Inhibition of aluminum corrosion using Opuntia extract”, Corrosion Sci., vol. 45, pp. 2485—2495, 2003.

5. S. Martinez “Inhibitory mechanism of mimosa tannin using molecular modeling and substitutional adsorption isotherms”, Mater. Chem. Phys, no. 77, pp. 97—102, 2002.

6. A.Y. El-Etre and M. Abdallah, “Natural honey as corrosion inhibitor for metals and alloys. II. C-steel in high saline water”, Corrosion Sci., no. 42, pp. 731—738, 2000.

7. S.A. Verma and G.N. Mehta, “Effect of acid extrets of powered seeds of eugenia jambolans on corrosion of mild steel in hcl-study by dc polarisation techniques”, SAEST, no. 4, pp. 98—93, 1997.

8. N. Kohler et al., “Green inhibitors for squeeze treatments: A promising alternative”, Petrol. Sci. Tech., no. 27, pp. 427—441, 2009.

9. J.J. Obrzut, “Metal corrosion eats away at everyone’s budget”, Iron Age, vol. 25, no. 4, pp. 45—48, 1982.

10. A.Y. El-Etre and Z. El-Tantany, “Iinhibition of metallic corrosion using Ficus Extract”, Portugaliae Electrochemica Acta, no. 24, pp. 347—356, 2006.

11. S. Baraca-Locmane et al., “Can green scale inhibitors replays phosphate scale inhibitors”, Petrol. Sci. Tech., no. 27, pp. 427—441, 2009.

12. K.S. Parikh and K.J. Joshi, “Use of Heena & Babul: Picking inhibitors for mild steel in 5 % hydrochloric acid”, Chem. Eng. World, no. 10, pp. 64—68, 2004.

13. Ляшенко Н.И. Биохимия хмеля и хмелепродуктов. — Житомир: “Полісся”, 2002. — 385 с.

14. Сумм Б.Д., Горюнов Ю.В. Физико-химические основы смачивания и растекания. — М.: Химия, 1976. — 230 с.

15. Антропов Л.И. Теоретична електрохімія. — К.: Либідь, 1993. — 544 с.

16. Zhang Da-quan et al., “Volatile corrosion inhibitor film formation on carbon steel surface and its inhibition effect on the atmospheric corrosion of carbon steel”, Appl. Surf. Sci., no. 253, pp. 1343—1348, 2006.

Downloads

Published

2013-02-28

Issue

No. 1 (2013): Engineering

Section

Art

License

Copyright (c) 2013 NTUU KPI Authors who publish with this journal agree to the following terms:

    1. Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under CC BY 4.0 that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.

    2. Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.

    3. Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work