The efficiency of coagulation treatment wastewater by reagent obtained from waste alumina production
DOI:
https://doi.org/10.20535/1810-0546.2015.6.51173Keywords:
Red mud, Acid activation, Coagulation, Dyes, Surfactants, Coagulation reagent, WastewaterAbstract
Background. The accumulation of industrial waste is one of the most urgent problems. So, development of complex technology utilization of wastes (red mud) is most economically and environmentally attractive way to solve the problem of red mud accumulation and getting of highly efficient purification reagents that was obtained from secondary raw materials.
Objective. The synthesis of coagulation reagents of water purification by acid activation of waste alumina production and test possibility of reagents using in wastewater treatment technology from the organic component.
Methods. Photometric analysis methods of initial components and products of coagulation cleaning.
Results. It is found that rational conditions of the red mud processing are: acid activation temperature from 150 to 250 °C; weight ratio of acid to red mud 0.5–2; process duration from 30 to 60 minutes. The high coagulation properties of reagents that was synthesized from waste was established and it was confirmed a high efficiency (82–96 %) treatment of wastewater that was contaminated with organic dyes and surfactants.
Conclusions. It was established that all synthesized samples of coagulation reagents from industrial wastes (red mud and hydrolytic sulfuric acid) are effective coagulants and can be used in water purification technology. Thus, when the “Bright-blue HF” dye concentration in the water 10 mg/l, cleaning efficiency was 96 % at the dose of coagulation reagent 200 mg/l.
References
P.V. Beresnevych et al., Environmental Protection in the Operation of Tailing Pits. Moscow, Russia: Nedra, 1993, pp. 5–29 (in Russian).
А.M. Ogorodnyk, “Ensuring environmental safety arrays-tailing (for example, Mykolayiv Alumina Plant)”, Naukovi Pratsi, vol. 157, pp. 55–61, 2011 (in Ukrainian).
H.M. Wang, “The comprehensive utilization of red mud (In Chinese)”, Shanxi Energy Conserv., vol. 11, pp. 58–61, 2011.
Y.F. Sun et al., “Technology for recovering iron from red mud by bayer process (In Chinese)”, Met. Mine, vol. 9, pp. 176–178, 2009.
L. Zhong and Y.F. Zhang, “Sub molten salt method recycling red mud”, Chin. J. Nonferrous Met., vol. 18, pp. 70–73, 2008.
D.I. Smirnov and V. Molchanova, “The investigation of sulfuric acid sorption recovery of scandium and uranium from red mud of alumina production”, Hydrometallurgy, vol. 45, pp. 249–259, 1997.
A. Xue et al., “The technological study and leaching kinetics of scandium from red mud (In Chinese)”, Nonferrous Metals Extr. Metall., vol. 2, pp. 51–53, 2010.
E. Kalkan, “Utilization of red mud as a stabilization material for the preparation of clay liners”, Eng. Geol., vol. 87, pp. 220–229, 2006.
I. Vangelatos et al., “Utilization of ferroalumina as raw material in the production of Ordinary Portland Cement”, Hazard. Mater., vol. 168, pp. 473–478, 2009.
P.X. Zhang, “Red mud making tile black granular materials (In Chinese)”, Multipurp. Util. Miner. Resour., vol. 3, pp. 41–43, 2000.
G. Xing and Z.Z Jiao, “The development of non-autoclaved brick made of red mud and fly ash”, Rare Metals Cemented Carbides, vol. 6, pp. 154–163, 1993.
V.A. Utkov et al., “Industrial methods of red mud processing”, in State, Problems and Trends in the National Economy of Using Red Mud. Nikolaev, Ukraine, 1999, p. 11.
V.H. Hubina and V.M. Kadoshnikov, “Red sludge Mykolayiv Alumina Plant is a valuable technological materials”, Heoloho-Mineralohichnyy Visnyk, vol. 2, pp. 122–126, 2005 (in Ukrainian).
Ya. Kalymon et al. “The research content of iron ions in hydrolytic sulfuric acid in the oboiled process”, Visnyk Natsional'noho Universytetu “L'vivs'ka Politekhnika”, vol. 761, pp. 16–20, 2013 (in Ukrainian).
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